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Study on the NOx release rule along the boiler during pulverized coal combustion

JIN Jing, ZHANG Zhongxiao, LI Ruiyang

《能源前沿（英文）》 2007年 第1卷 第1期   页码 91-95 doi: 10.1007/s11708-007-0009-7

摘要： Numerical simulation and experimental study on NO release along the boiler during pulverized coal combustion have been conducted. With the increase of temperature the NO emission increased and the peak value of NO release moved forward. But when the temperature increased to a certain degree, NO emission began to reduce. NO emission increased with the increase of nitrogen content of coal. The peak value of NO release moved backwards with the increase of coal rank. NO emission increased obviously with the increase of stoichiometric ratio. There existed a critical average diameter of the pulverized coal (). If "d, NO emission reduced with the decrease of pulverized coal size. If >, NO emission reduced with the increase of the pulverized coal size. The results showed that the simulation results are in agreement with the experimental results for concentration distribution of NO along the axis of the furnace.
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Optimization of Venturi tube design for pipeline pulverized coal flow measurements

WU Zhansong, XIE Fei

《能源前沿（英文）》 2008年 第2卷 第4期   页码 369-373 doi: 10.1007/s11708-008-0072-8

摘要： A Venturi flow meter was designed to accurately measure the mass flow rate of pulverized coal in power plant pipelines. Numerical simulations of the dilute turbulent gas-solid two-phase flow in a horizontal Venturi tube were used to study the effects of Venturi tube geometry on the pressure distribution in the mixture. The results show that Venturi tube geometry strongly influences the metering of the dilute gas-particle two-phase flow. The geometry can be optimized to improve the precision of the measurement and ensure stable measurements. Furthermore, the geometries of three types of Venturi tubes were optimized for an experimental study of pulverized coal mass flow rate measurements.

关键词： gas-solid two-phase     geometry     gas-particle two-phase     Numerical     flow    

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Effects of pyrolyzed semi-char blend ratio on coal combustion and pollution emission in a 0.35 MW pulverizedcoal-fired furnace

Yonghong YAN, Liutao SUN, Zhengkang PENG, Hongliang QI, Li LIU, Rui SUN

《能源前沿（英文）》 2021年 第15卷 第1期   页码 78-90 doi: 10.1007/s11708-020-0678-z

摘要： The effects of blend ratio on combustion and pollution emission characteristics for co-combustion of Shenmu pyrolyzed semi-char (SC), i.e., residuals of the coal pyrolysis chemical processing, and Shenhua bituminous coal (SB) were investigated in a 0.35 MW pilot-scale pulverized coal-fired furnace. The gas temperature and concentrations of gaseous species (O , CO, CO , NO and HCN) were measured in the primary combustion zone at different blend ratios. It is found that the standoff distance of ignition changes monotonically from 132 to 384 mm with the increase in pyrolyzed semi-char blend ratio. The effects on the combustion characteristics may be neglected when the blend ratio is less than 30%. Above the 30% blend ratio, the increase in blend ratio postpones ignition in the primary stage and lowers the burnout rate. With the blend ratio increasing, NO emission at the furnace exit is smallest for the 30% blend ratio and highest for the 100% SC. The NO concentration was 425 mg/m at 6% O and char burnout was 76.23% for the 45% blend ratio. The above results indicate that the change of standoff distance and NO emission were not obvious when the blend ratio of semi-char is less than 45%, and carbon burnout changed a little at all blend ratios. The goal of this study is to achieve blending combustion with a large proportion of semi-char without great changes in combustion characteristics. So, an SC blend ratio of no more than 45% can be suitable for the burning of semi-char.

关键词： pulverized-coal combustion     pyrolyzed semi-char     ignition characteristics     pollution emission     char burnout     blend ratio    

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Influence of mass air flow ratio on gas-particle flow characteristics of a swirl burner in a 29 MW pulverizedcoal boiler

Rong YAN, Zhichao CHEN, Shuo GUAN, Zhengqi LI

《能源前沿（英文）》 2021年 第15卷 第1期   页码 68-77 doi: 10.1007/s11708-020-0697-9

摘要： In a gas/particle two-phase test facility, a three-component particle-dynamics anemometer was used to measure the characteristics of gas/particle two-phase flows in a 29 megawatt (MW) pulverized coal industrial boiler equipped with a new type of swirling pulverized coal burner. The distributions of three-dimensional gas/particle velocity, particle volume flux, and particle size distribution were measured under different working conditions. The mean axial velocity and the particle volume flux in the central region of the burner outlet were found to be negative. This indicated that a central recirculation zone was formed in the center of the burner. In the central recirculation zone, the absolute value of the mean axial velocity and the particle volume flux increased when the external secondary air volume increased. The size of the central reflux zone remained stable when the air volume ratio changed. Along the direction of the jet, the peak value formed by the tertiary air gradually moved toward the center of the burner. This tertiary air was mixed with the peak value formed by the air in the adiabatic combustion chamber after the cross-section of / = 0.7. Large particles were concentrated near the wall area, and the particle size in the recirculation zone was small.

关键词： industrial pulverized coal boiler     swirl burner     air/particle flow     particle dynamic analyzer (PDA)    

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Experimental studies of ash film fractions based on measurement of cenospheres geometry in pulverizedcoal combustion

Siqi LIU, Yanqing NIU, Liping WEN, Yang LIANG, Bokang YAN, Denghui WANG, Shi’en HUI

《能源前沿（英文）》 2021年 第15卷 第1期   页码 91-98 doi: 10.1007/s11708-020-0806-9

摘要： In pulverized coal particle combustion, part of the ash forms the ash film and exerts an inhibitory influence on combustion by impeding the diffusion of oxygen to the encapsulated char core, while part of the ash diffuses toward the char core. Despite the considerable ash effects on combustion, the fraction of ash film still remains unclear. However, the research of the properties of cenospheres can be an appropriate choice for the fraction determination, being aware that the formation of cenospheres is based on the model of coal particles with the visco-plastic ash film and a solid core. The fraction of ash film is the ratio of the measuring mass of ash film and the total ash in coal particle. In this paper, the Huangling bituminous coal with different sizes was burnt in a drop-tube furnace at 1273, 1473, and 1673 K with air as oxidizer. A scanning electron microscope (SEM) and cross-section analysis have been used to study the geometry of the collected cenospheres and the effects of combustion parameters on the fraction of ash film. The results show that the ash film fraction increases with increasing temperature and carbon conversion ratio but decreases with larger sizes of coal particles. The high fraction of ash film provides a reasonable explanation for the extinction event at the late burnout stage. The varied values of ash film fractions under different conditions during the dynamic combustion process are necessary for further development of kinetic models.

关键词： ash film fraction     cenospheres     coal combustion     fly ash    

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NO control in large-scale power plant boilers through superfine pulverized coal technology

YIN Jie, WEI Dunsong, YIN Jie, REN Jianxing

《能源前沿（英文）》 2008年 第2卷 第4期   页码 461-465 doi: 10.1007/s11708-008-0057-7

摘要： Superfine pulverized coal technology can effectively reduce NO emission in coal-fired power plant boilers. It can also economize the cost of the power plant and improve the use of the ash in the flue gas. Superfine pulverized coal technology, which will be widely used in China, includes common superfine pulverized coal technology and superfine pulverized coal reburning technology. The use of superfine pulverized coal instead of common coal in large-scale power plants will not only reduce more than 30% of NO emission but also improve the thermal efficiency of the boiler.
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Numerical simulation of combustion characteristics at different coal concentrations in bituminous coal

Chunlong LIU, Qunyi ZHU, Zhengqi LI, Qiudong ZONG, Yiquan XIE, Lingyan ZENG

《能源前沿（英文）》 2013年 第7卷 第2期   页码 255-262 doi: 10.1007/s11708-013-0255-9

摘要： With the objective of producing a full-scale tiny-oil ignition burner, identical to the burner used in an 800 MWe utility boiler, numerical simulations were performed using Fluent 6.3.26 to study the progress of ignition for four coal concentration settings covering sub-operation conditions prevailing during the experiments performed with the burner. The numerical simulations conformed to the experimental results, demonstrating the suitability of the model used in the calculations. Simulations for a coal concentration of 0.40 kg/kg corresponding to a single burner operating at its rated output were also conducted, which indicated that gas temperatures along the burner centerline were high. As gas flowed to the burner nozzle, the high-temperature region expanded, ensuring a successful pulverized-coal ignition. With increasing coal concentration (0.08–0.40 kg/kg), the gas temperature along the burner centerline and at the first and second combustion chamber exits decreased at the equivalent radial points. At the center of the second combustion chamber exit, the O concentrations were almost depleted for the five coal concentrations, while the CO concentrations peaked.

关键词： numerical simulation     tiny-oil ignition burner     pulverized coal     temperature field    

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Techno-economic assessment of pulverized coal boilers and IGCC power plants with CO 2 capture

Y. HUANG, S. REZVANI, D. McILVEEN-WRIGHT, N. HEWITT, J. MONDOL, A. MINCHENER,

《化学科学与工程前沿（英文）》 2010年 第4卷 第2期   页码 196-206 doi: 10.1007/s11705-009-0237-y

摘要： The current studies on power plant technologies suggest that Integrated Gasification Combined Cycle (IGCC) systems are an effective and economic CO capture technology pathway. In addition, the system in conventional configuration has the advantage of being more “CO capture ready” than other technologies. Pulverized coal boilers (PC) have, however, proven high technical performance attributes and are economically often most practical technologies. To highlight the pros and cons of both technologies in connection with an integrated CO capture, a comparative analysis of ultrasupercritical PC and IGCC is carried out in this paper. The technical design, the mass and energy balance and the system optimizations are implemented by using the ECLIPSE chemical plant simulation software package. Built upon these technologies, the COcapture facilities are incorporated within the system. The most appropriate CO capture systems for the PC system selected for this work are the oxy-fuel system and the postcombustion scheme using Monoethanolamine solvent scrubber column (MEA). The IGCC systems are designed in two configurations: Water gas shift reactor and Selexol-based separation. Both options generate CO-rich and hydrogen rich-gas streams. Following the comparative analysis of the technical performance attributes of the above cycles, the economic assessment is carried out using the economic toolbox of ECLIPSE is seamlessly connected to the results of the mass and energy balance as well as the utility usages. The total cost assessment is implemented according to the step-count exponential costing method using the dominant factors and/or a combination of parameters. Subsequently, based on a set of assumptions, the net present value estimation is implemented to calculate the breakeven electricity selling prices and the CO avoidance cost.

关键词： breakeven electricity     ECLIPSE     technical performance     appropriate     economic    

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NOx and H2S formation in the reductive zone of air-staged combustion of pulverized

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

《能源前沿（英文）》 2021年 第15卷 第1期   页码 4-13 doi: 10.1007/s11708-020-0804-y

摘要： Low NO combustion of blended coals is widely used in coal-fired boilers in China to control NO emission; thus, it is necessary to understand the formation mechanism of NO and H S during the combustion of blended coals. This paper focused on the investigation of reductive gases in the formation of NO and H S in the reductive zone of blended coals during combustion. Experiments with Zhundong (ZD) and Commercial (GE) coal and their blends with different mixing ratios were conducted in a drop tube furnace at 1200°C–1400°C with an excessive air ratio of 0.6–1.2. The coal conversion and formation characteristics of CO, H S, and NO in the fuel-rich zone were carefully studied under different experimental conditions for different blend ratios. Blending ZD into GE was found to increase not only the coal conversion but also the concentrations of CO and H S as NO reduction accelerated. Both the CO and H S concentrations inblended coal combustion increase with an increase in the combustion temperature and a decrease in the excessive air ratio. Based on accumulated experimental data, one interesting finding was that NO and H S from blended coal combustion were almost directly dependent on the CO concentration, and the CO concentration of the blended coal combustion depended on the single char gasification conversion.Thus, CO, NO , and H S formation characteristics from blended coal combustion can be well predicted by single char gasification kinetics.

关键词： blended coal combustion     NOx formation     H2S formation     air staged combustion    

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Numerical simulation of bituminous coal combustion in a full-scale tiny-oil ignition burner: influence

Zhengqi LI, Chunlong LIU, Xiang ZHANG, Lingyan ZENG, Zhichao CHEN

《能源前沿（英文）》 2012年 第6卷 第3期   页码 296-303 doi: 10.1007/s11708-012-0191-0

摘要： The progression of ignition was numerically simulated with the aim of realizing a full-scale tiny-oil ignition burner that is identical to the burner used in an 800 MWe utility boiler. The numerical simulations were conducted for four excess air ratios, 0.56, 0.75, 0.98 and 1.14 (corresponding to primary air velocities of 17, 23, 30 and 35 m/s, respectively), which were chosen because they had been used previously in practical experiments. The numerical simulations agreed well with the experimental results, which demonstrate the suitability of the model used in the calculations. The gas temperatures were high along the center line of the burner for the four excess air ratios. The flame spread to the burner wall and the high-temperature region was enlarged in the radial direction along the primary air flow direction. The O concentrations for the four excess air ratios were 0.5%, 1.1%, 0.9% and 3.0% at the exit of the second combustion chamber. The CO peak concentration was very high with values of 7.9%, 9.9%, 11.3% and 10.6% for the four excess air ratios at the exit of the second combustion chamber.

关键词： numerical simulation     tiny-oil ignition burner     pulverized coal     temperature field    

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新一代煤化工和洁净煤技术利用现状分析与对策建议

谢克昌

《中国工程科学》 2003年 第5卷 第6期   页码 15-24

摘要：

在论述煤炭的战略地位、利用现状和分析新一代煤化工技术与洁净煤技术利用现状的基础上，以科学规划所应遵循的原则，结合作者的科研实践，提出了我国发展新一代煤化工和洁净煤利用技术的建议。

关键词： 煤化工     洁净煤技术     对策    

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Management and Practice of Large-Scale Modern Coal Enterprises

An Wang

《工程管理前沿（英文）》 2014年 第1卷 第1期   页码 13-17 doi: 10.15302/J-FEM-2014004

摘要： As the coal-dominated energy structure will remain unchanged in the short term, the sustainable development of the coal industry is still serving as one of the foundations for the sound development of the national economy. The construction of modernized mines based on "four orientations", that is, orientations of scale production, modern technology and equipment, informationized management and professional working team, has been rapidly enhancing its development in the recent decade. However, in the next decade or an even longer period, the industry, with the energy centre shifting to the West of China, will be exposed to new options and development in the layout, structure, model, technology, etc.

关键词： coal industry     sustainable development     the four-orientation model    

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Managing Innovation: Accelerating the Development of Clean Coal Technology

Ya-juan Sun,Guo-qing Wang,Yan Wang,Ning Zhang,Zhen-qi Zhu

《工程管理前沿（英文）》 2015年 第2卷 第1期   页码 86-92 doi: 10.15302/J-FEM-2015013

摘要： Coal gasification technology concerns the clean, efficient utilization of coal, providing a core solution to address its negative environmental image and impact. Presently, China is pursuing the development of coal gasification technology despite industry setbacks, limited progress and elusive solutions due to limited specialty materials, technological shortfalls and intellectual expertise. The most prominent challenges to overcome include unbalanced research and project scale development issues followed by an excessive emphasis on equipment manufacturing rather than responsible management practices. The ENN Group explored these industry shortcomings to develop a comprehensive management philosophy that is specifically tailored to overcome these fundamental hurdles. Such innovative solutions include the Centralized Innovation Camp, TRIZ (Theory of Inventive Problem Solving) training, Extensive Alliance Network and enhanced process management, focusing upon engineering, quality assurance and process efficiency with the overall objective of industrial scale application. As a result, ENN’s Clean Coal Technologies include: Coal Hydro-gasification, Supercritical Coal Gasification, Catalytic Coal Gasification and Underground Coal Gasification, having successfully completed all pilot plant testing requirements and the construction of demonstration commercial units.

关键词： coal technology     coal gasification     innovation     management     clean     ENN    

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On the fouling mechanism of polysulfone ultrafiltration membrane in the treatment of coal gasification

Xue Zou,Jin Li

《化学科学与工程前沿（英文）》 2016年 第10卷 第4期   页码 490-498 doi: 10.1007/s11705-016-1600-4

摘要： Membrane fouling has been investigated by using a polysulfone ultrafiltration membrane with the molecular weight cutoff of 20 kDa to treat crushed coal pressurized gasification wastewater. Under the conditions of different feed pressures, the permeate flux declines and rejection coefficients of pollutants referring to three parameters (total organic carbon (TOC), chroma and turbidity) were studied. The membrane fouling mechanism was simulated with three classical membrane fouling models. The membrane image and pollutants were analyzed by scanning electron microscopy and gas chromatography-mass spectrography (GC-MS). The results indicate that the permeate flux decreases with volume reduction factor before reaching a constant value. The rejection coefficients were also measured: = 70.5%, = 84.9% and = 91%. Further analysis shows that the higher the feed pressure is, the sooner the permeate flux reaches constant value and the more sharply the permeate flux declines. Constant flux indicates a nonlinear growth with feed pressure ( ): when equals 1.2 bar, the mark for the critical flux, slight membrane fouling occurs; when exceeds 1.2 bar, cake layer pollution aggravates. Also the rejection coefficients of global pollutant increases slightly with , suggesting the possibility of cake compression when exceeds 1.2 bar. Through regression analysis, the fouling of polysulfone ultrafiltration membrane could be fitted very well by cake filtration model. The membrane pollutants were identified as phthalate esters and long-chain alkenes by GC-MS, and a certain amount of inorganic pollutants by X-ray photoelectron spectroscopy.

关键词： membrane fouling     ultrafiltration membrane     coal gasification wastewater     rejection coefficient    

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标题 作者 时间 类型 操作

Study on the NOx release rule along the boiler during pulverized coal combustion

JIN Jing, ZHANG Zhongxiao, LI Ruiyang

期刊论文

Optimization of Venturi tube design for pipeline pulverized coal flow measurements

WU Zhansong, XIE Fei

期刊论文

Effects of pyrolyzed semi-char blend ratio on coal combustion and pollution emission in a 0.35 MW pulverizedcoal-fired furnace

Yonghong YAN, Liutao SUN, Zhengkang PENG, Hongliang QI, Li LIU, Rui SUN

期刊论文

Influence of mass air flow ratio on gas-particle flow characteristics of a swirl burner in a 29 MW pulverizedcoal boiler

Rong YAN, Zhichao CHEN, Shuo GUAN, Zhengqi LI

期刊论文

Experimental studies of ash film fractions based on measurement of cenospheres geometry in pulverizedcoal combustion

Siqi LIU, Yanqing NIU, Liping WEN, Yang LIANG, Bokang YAN, Denghui WANG, Shi’en HUI

期刊论文

NO control in large-scale power plant boilers through superfine pulverized coal technology

YIN Jie, WEI Dunsong, YIN Jie, REN Jianxing

期刊论文

Numerical simulation of combustion characteristics at different coal concentrations in bituminous coal

Chunlong LIU, Qunyi ZHU, Zhengqi LI, Qiudong ZONG, Yiquan XIE, Lingyan ZENG

期刊论文

Techno-economic assessment of pulverized coal boilers and IGCC power plants with CO 2 capture

Y. HUANG, S. REZVANI, D. McILVEEN-WRIGHT, N. HEWITT, J. MONDOL, A. MINCHENER,

期刊论文

NOx and H2S formation in the reductive zone of air-staged combustion of pulverized

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

期刊论文

Numerical simulation of bituminous coal combustion in a full-scale tiny-oil ignition burner: influence

Zhengqi LI, Chunlong LIU, Xiang ZHANG, Lingyan ZENG, Zhichao CHEN

期刊论文

Innovative approach of low carbon and efficient utilization of coal resources: The polygeneration systemof a combination of the gasified coal gas and the pyrolyzed coal gas to form the synthetic gas

Kechang XIE, Fan LI

期刊论文

新一代煤化工和洁净煤技术利用现状分析与对策建议

谢克昌

期刊论文

Management and Practice of Large-Scale Modern Coal Enterprises

An Wang

期刊论文

Managing Innovation: Accelerating the Development of Clean Coal Technology

Ya-juan Sun,Guo-qing Wang,Yan Wang,Ning Zhang,Zhen-qi Zhu

期刊论文

On the fouling mechanism of polysulfone ultrafiltration membrane in the treatment of coal gasification

Xue Zou,Jin Li

期刊论文